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Goals from Jack Collison, Junior Stanislas, Guillermo Franco and penalties from Carlton Cole and Luis Jimenez put the Hammers 5-0 up before Burnley staged a late comeback with the game ending 5-3.
The result saw Gianfranco Zola's side move out to a best price 6/1 with William Hill to be relegated this season.
bet365 offer 15/8 this morning on Burnley returning to the Championship.
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